C:Documents and Settings is a hidden folder. As you see in the following commandprompt, it is a junction to C:Users to stay backwards compatible. Just disable the view of hidden files and folders (Tools -> Folder Options -> View in Windows Explorer), and it won’t bother you again! 😉
Microsoft Windows [Version 6.0.6001]
Copyright (c) 2006 Microsoft Corporation. All rights reserved.
C:UsersAdministrator>dir c: /a:h
Volume in drive C is WIN2008
Volume Serial Number is B098-05D1
Directory of c:
01/19/2008 11:33 AM $Recycle.Bin
03/16/2008 01:58 AM Boot
01/19/2008 09:45 AM 333,203 bootmgr
01/19/2008 04:21 PM Documents and Settings [C:Users]
03/17/2008 12:42 AM MSOCache
03/29/2008 02:42 PM 4,607,066,112 pagefile.sys
03/31/2008 11:11 PM ProgramData
03/16/2008 01:00 AM System Volume Information
2 File(s) 4,607,399,315 bytes
6 Dir(s) 46,130,495,488 bytes free
C:UsersAdministrator> 